2024 

Wu, L.-F., Zhang, J., Cornwell-Arquitt, R., Hendrix, D.A., Radakovic, A., Szostak, J.W.*, 2024. Selective Nonenzymatic Formation of Biologically Common RNA Hairpins. Angew Chem Int Ed e202417370. PDF

Duzdevich, D.*, Carr, C.E., Colville, B.W.F., Aitken, H.R.M., Szostak, J.W., 2024. Overcoming nucleotide bias in the nonenzymatic copying of RNA templates. Nucleic Acids Research gkae982. PDF

Radakovic, A., Lewicka, A., Todisco, M., Aitken, H.R.M., Weiss, Z., Kim, S., Bannan, A., Piccirilli, J.A.*, Szostak, J.W.*, 2024. A potential role for RNA aminoacylation prior to its role in peptide synthesis. Proc. Natl. Acad. Sci. U.S.A. 121, e2410206121. PDF

Agrawal, A., Radakovic, A., Vonteddu, A., Rizvi, S., Huynh, V.N., Douglas, J.F., Tirrell, M.V.*, Karim, A.*, Szostak, J.W.*, 2024. Did the exposure of coacervate droplets to rain make them the first stable protocells? Sci. Adv. 10, eadn9657. PDF

Jia, X., Zhang, S.J., Zhou, L., Szostak, J.W.*, 2024. Constraints on the emergence of RNA through non-templated primer extension with mixtures of potentially prebiotic nucleotides. Nucleic Acids Research 52, 5451–5464. PDF

Jia, X., Fang, Z., Kim, S.C., Ding, D., Zhou, L., Szostak, J.W.*, 2024. Diaminopurine in Nonenzymatic RNA Template Copying. J. Am. Chem. Soc. 146, 15897–15907. PDF

Ravasio, R., Husain, K., Evans, C.G., Phillips, R., Ribezzi, M., Szostak, J.W.*, Murugan, A.*, 2024. A minimal scenario for the origin of non-equilibrium order. PDF

Mittal, S., Nisler, C., Szostak, J.W.*, 2024. Simulations predict preferred Mg2+ coordination in a nonenzymatic primer-extension reaction center. Biophysical Journal 123, 1579–1591. PDF

Todisco, M., Radakovic, A., Szostak, J.W.*, 2024. RNA Complexes with Nicks and Gaps: Thermodynamic and Kinetic Effects of Coaxial Stacking and Dangling Ends. J. Am. Chem. Soc. 146, 18083–18094. PDF

Fang, Z., Pazienza, L.T., Zhang, J., Tam, C.P., Szostak, J.W.*, 2024. Catalytic Metal Ion–Substrate Coordination during Nonenzymatic RNA Primer Extension. J. Am. Chem. Soc. 146, 10632–10639. PDF

Todisco, M., Ding, D., Szostak, J.W.*, 2024. Transient states during the annealing of mismatched and bulged oligonucleotides. Nucleic Acids Research 52, 2174–2187. PDF

Cohen, Z.R., Ding, D., Zhou, L., DasGupta, S., Haas, S., Sinclair, K.P., Todd, Z.R., Black, R.A., Szostak, J.W.*, Catling, D.C.*, 2024. Natural soda lakes provide compatible conditions for RNA and membrane function that could have enabled the origin of life. PNAS Nexus 3, pgae084. PDF

Ding, D., Fang, Z., Kim, S.C., O’Flaherty, D.K., Jia, X., Stone, T.B., Zhou, L.*, Szostak, J.W.*, 2024. Unusual Base Pair between Two 2-Thiouridines and Its Implication for Nonenzymatic RNA Copying. J. Am. Chem. Soc. 146, 3861–3871. PDF

DasGupta, S., Weiss, Z., Nisler, C., Szostak, J.W.*, 2024. Evolution of the substrate specificity of an RNA ligase ribozyme from phosphorimidazole- to triphosphate-activation (preprint) PDF

Radakovic, A., Lewicka, A., Todisco, M., Aitken, H.R.M., Weiss, Z., Kim, S., Bannan, A., Piccirilli, J.A., Szostak, J.W., 2024. Structure-guided aminoacylation and assembly of chimeric RNAs. (preprint) PDF

Kufner, C.L., Crucilla, S., Ding, D., Stadlbauer, P., Šponer, J., Szostak, J.W., Sasselov, D.D., Szabla, R.*, 2024. Photoinduced charge separation and DNA self-repair depend on sequence directionality and stacking pattern. Chem. Sci. 15, 2158–2166. PDF

Strom, K.R., Szostak, J.W.*, 2024. Sequence Information Transfer in Oligoarylacetylenes. ChemistryEurope 2, e202300073. PDF

 

2023

Toparlak, Ö.D., Sebastianelli, L., Egas Ortuno, V., Karki, M., Xing, Y., Szostak, J.W.*, Krishnamurthy, R.*, Mansy, S.S.*, 2023. Cyclophospholipids Enable a Protocellular Life Cycle. ACS Nano 17, 23772–23783. PDF 

Fan, Z., Deckel, Y., Lowe, L.A., Loo, D.W.K., Yomo, T., Szostak, J.W., Nisler, C.*, Wang, A.*, 2023. Lipid Exchange Promotes Fusion of Model Protocells. Small Methods 7, 2300126. PDF

Lelyveld, V.S., Fang, Z., Szostak, J.W.*, 2023. Trivalent rare earth metal cofactors confer rapid NP-DNA polymerase activity. Science 382, 423–429. PDF

Ashwood, B., Jones, M.S., Radakovic, A., Khanna, S., Lee, Y., Sachleben, J.R., Szostak, J.W., Ferguson, A.L., Tokmakoff, A.*, 2023. Thermodynamics and kinetics of DNA and RNA dinucleotide hybridization to gaps and overhangs. Biophysical Journal 122, 3323–3339. PDF

DasGupta, S., Zhang, S., Szostak, J.W.*, 2023. Molecular Crowding Facilitates Ribozyme-Catalyzed RNA Assembly. ACS Cent. Sci. 9, 1670–1678. PDF

DasGupta, S., Zhang, S.J., Smela, M.P., Szostak, J.W.*, 2023. RNA‐Catalyzed RNA Ligation within Prebiotically Plausible Model Protocells. Chemistry A European J 29, e202301376. PDF

Ding, D., Zhang, S.J., Szostak, J.W.*, 2023. Enhanced nonenzymatic RNA copying with in-situ activation of short oligonucleotides. Nucleic Acids Research 51, 6528–6539. PDF

Aitken, H.R.M., Wright, T.H., Radakovic, A., Szostak, J.W.*, 2023. Small-Molecule Organocatalysis Facilitates In Situ Nucleotide Activation and RNA Copying. J. Am. Chem. Soc. 145, 16142–16149. PDF 

Zhang, S.J., Lowe, L.A., Anees, P., Krishnan, Y., Fai, T.G., Szostak, J.W., Wang, A.*, 2023. Passive endocytosis in model protocells. Proc. Natl. Acad. Sci. U.S.A. 120, e2221064120. PDF

Ding, D., Zhou, L., Mittal, S., Szostak, J.W.*, 2023. Experimental Tests of the Virtual Circular Genome Model for Nonenzymatic RNA Replication. J. Am. Chem. Soc. 145, 7504–7515. PDF

Mittal, S., Nisler, C., Szostak, J.W.*, 2023. Simulations predict preferred Mg 2+ coordination in a nonenzymatic primer extension reaction center. PDF

Crucilla, S.J., Ding, D., Lozano, G.G., Szostak, J.W., Sasselov, D.D., Kufner, C.L.*, 2023. UV-driven self-repair of cyclobutane pyrimidine dimers in RNA. Chem. Commun. 59, 13603–13606. PDF

2022 

Strom, K.R., Szostak, J.W.,* 2022. Folding and Duplex Formation in Sequence-Defined Aniline Benzaldehyde Oligoarylacetylenes. J. Am. Chem. Soc. 144, 18350–18358. PDF

Todisco, M., Szostak, J.W.*, 2022. Hybridization kinetics of out-of-equilibrium mixtures of short RNA oligonucleotides. Nucleic Acids Research 50, 9647–9662. PDF

Wu, L.-F., Liu, Z., Roberts, S.J., Su, M., Szostak, J.W.*, Sutherland, J.D.*, 2022. Template-Free Assembly of Functional RNAs by Loop-Closing Ligation. J. Am. Chem. Soc. 144, 13920–13927. PDF

Zhang, S.J., Duzdevich, D., Ding, D., Szostak, J.W.*, 2022. Freeze-thaw cycles enable a prebiotically plausible and continuous pathway from nucleotide activation to nonenzymatic RNA copying. Proc. Natl. Acad. Sci. U.S.A. 119, e2116429119. PDF

Ding, D., Zhou, L., Giurgiu, C., Szostak, J.W.*, 2022. Kinetic explanations for the sequence biases observed in the nonenzymatic copying of RNA templates. Nucleic Acids Research 50, 35–45. PDF

2021

Giurgiu, C., Fang, Z., Aitken, H.R.M., Kim, S.C., Pazienza, L., Mittal, S., Szostak, J.W.*, 2021. Structure–Activity Relationships in Nonenzymatic Template‐Directed RNA Synthesis. Angew Chem Int Ed 60, 22925–22932. PDF

Duzdevich, D., Carr, C.E., Ding, D., Zhang, S.J., Walton, T.S., Szostak, J.W.*, 2021. Competition between bridged dinucleotides and activated mononucleotides determines the error frequency of nonenzymatic RNA primer extension. Nucleic Acids Research 49, 3681–3691. PDF

Kim, S.C., O’Flaherty, D.K., Giurgiu, C., Zhou, L., Szostak, J.W.*, 2021. The Emergence of RNA from the Heterogeneous Products of Prebiotic Nucleotide Synthesis. J. Am. Chem. Soc. 143, 3267–3279. PDF

Radakovic, A., Wright, T.H., Lelyveld, V.S., Szostak, J.W.*, 2021. A Potential Role for Aminoacylation in Primordial RNA Copying Chemistry. Biochemistry 60, 477–488. PDF

Zhang, W., Kim, S.C., Tam, C.P., Lelyveld, V.S., Bala, S., Chaput, J.C., Szostak, J.W.*, 2021. Structural interpretation of the effects of threo-nucleotides on nonenzymatic template-directed polymerization. Nucleic Acids Research 49, 646–656. PDF

Zhou, L., Ding, D., Szostak, J.W.*, 2021. The virtual circular genome model for primordial RNA replication. RNA 27, 1–11. PDF

2020 

Strom, K.R., Szostak, J.W.*, 2020. Solid-Phase Synthesis of Sequence-Defined Informational Oligomers. J. Org. Chem. 85, 13929–13938. PDF

Kindt, J.T., Szostak, J.W*., Wang, A.*, 2020. Bulk Self-Assembly of Giant, Unilamellar Vesicles. ACS Nano 14, 14627–14634. PDF 

O’Flaherty, D.#, Zhou, L.#, Szostak, J.*, 2020. Nonenzymatic RNA-templated Synthesis of N3′→P5′ Phosphoramidate DNA. BIO-PROTOCOL 10. PDF

Zhou, L., O’Flaherty, D.K., Szostak, J.W.*, 2020. Assembly of a Ribozyme Ligase from Short Oligomers by Nonenzymatic Ligation. J. Am. Chem. Soc. 142, 15961–15965. PDF

Zhang, S.J., Duzdevich, D., Szostak, J.W.*, 2020. Potentially Prebiotic Activation Chemistry Compatible with Nonenzymatic RNA Copying. J. Am. Chem. Soc. 142, 14810–14813. PDF

Zhou, L., O’Flaherty, D.K., Szostak, J.W.*, 2020. Template‐Directed Copying of RNA by Non‐enzymatic Ligation. Angew Chem Int Ed 59, 15682–15687. PDF

Duzdevich, D., Carr, C.E., Szostak, J.W.*, 2020. Deep sequencing of non-enzymatic RNA primer extension. Nucleic Acids Research 48, e70–e70. PDF

Todd, Z.R.*, Fahrenbach, A.C., Ranjan, S., Magnani, C.J., Szostak, J.W., Sasselov, D.D., 2020. Ultraviolet-Driven Deamination of Cytidine Ribonucleotides Under Planetary Conditions. Astrobiology 20, 878–888. PDF 

Yildirim, O., Izgu, E.C., Damle, M., Chalei, V., Ji, F., Sadreyev, R.I., Szostak, J.W., Kingston, R.E.*, 2020. S-phase Enriched Non-coding RNAs Regulate Gene Expression and Cell Cycle Progression. Cell Reports 31, 107629. PDF

Lelyveld, V.S., Zhang, W., Szostak, J.W.*, 2020. Synthesis of phosphoramidate-linked DNA by a modified DNA polymerase. Proc. Natl. Acad. Sci. U.S.A. 117, 7276–7283. PDF

Walton, T., DasGupta, S., Duzdevich, D., Oh, S.S., Szostak, J.W.*, 2020. In vitro selection of ribozyme ligases that use prebiotically plausible 2-aminoimidazole–activated substrates. Proc. Natl. Acad. Sci. U.S.A. 117, 5741–5748. PDF

Kim, S.C., Zhou, L., Zhang, W., O’Flaherty, D.K., Rondo-Brovetto, V., Szostak, J.W.*, 2020. A Model for the Emergence of RNA from a Prebiotically Plausible Mixture of Ribonucleotides, Arabinonucleotides, and 2′-Deoxynucleotides. J. Am. Chem. Soc. 142, 2317–2326. PDF

Chizzolini, F., Passalacqua, L.F.M., Oumais, M., Dingilian, A.I., Szostak, J.W.*, Lupták, A.*, 2020. Large Phenotypic Enhancement of Structured Random RNA Pools. J. Am. Chem. Soc. 142, 1941–1951. PDF

2019 

Zhou, L., Kim, S.C., Ho, K.H., O’Flaherty, D.K., Giurgiu, C., Wright, T.H., Szostak, J.W.*, 2019. Non-enzymatic primer extension with strand displacement. eLife 8, e51888. PDF

Wang, A., Szostak, J.W.*, 2019. Lipid constituents of model protocell membranes. Emerging Topics in Life Sciences 3, 537–542. PDF

Wright, T.H., Giurgiu, C., Zhang, W., Radakovic, A., O’Flaherty, D.K., Zhou, L., Szostak, J.W.*, 2019. Prebiotically Plausible “Patching” of RNA Backbone Cleavage through a 3′–5′ Pyrophosphate Linkage. J. Am. Chem. Soc. 141, 18104–18112. PDF

Lelyveld, V.S., O’Flaherty, D.K., Zhou, L., Izgu, E.C., Szostak, J.W.*, 2019. DNA polymerase activity on synthetic N3′→P5′ phosphoramidate DNA templates. Nucleic Acids Research 47, 8941–8949. PDF

Todd, Z.R.*, Szabla, R., Szostak, J.W., Sasselov, D.D., 2019. UV photostability of three 2-aminoazoles with key roles in prebiotic chemistry on the early earth. Chem. Commun. 55, 10388–10391.PDF

Zhang, W., Pal, A., Ricardo, A., Szostak, J.W.*, 2019. Template-Directed Nonenzymatic Primer Extension Using 2-Methylimidazole-Activated Morpholino Derivatives of Guanosine and Cytidine. J. Am. Chem. Soc. 141, 12159–12166. PDF 

O’Flaherty, D.K., Zhou, L., Szostak, J.W.*, 2019. Nonenzymatic Template-Directed Synthesis of Mixed-Sequence 3′-NP-DNA up to 25 Nucleotides Long Inside Model Protocells. J. Am. Chem. Soc. 141, 10481–10488. PDF 

Walton, T., Zhang, W., Li, L., Tam, C.P., Szostak, J.W.*, 2019. The Mechanism of Nonenzymatic Template Copying with Imidazole‐Activated Nucleotides. Angew Chem Int Ed 58, 10812–10819. PDF

Strom, K.R.*, Szostak, J.W., Prywes, N.*, 2019. Transfer of Sequence Information and Replication of Diimine Duplexes. J. Org. Chem. 84, 3754–3761. PDF

Walton, T., Pazienza, L., Szostak, J.W.*, 2019. Template-Directed Catalysis of a Multistep Reaction Pathway for Nonenzymatic RNA Primer Extension. Biochemistry 58, 755–762. PDF

Matsushita-Ishiodori, Y., Hanczyc, M.M., Wang, A., Szostak, J.W., Yomo, T.*, 2019. Using Imaging Flow Cytometry to Quantify and Optimize Giant Vesicle Production by Water-in-oil Emulsion Transfer Methods. Langmuir 35, 2375–2382. PDF

Wang, A.*, Chan Miller, C., Szostak, J.W.*, 2019. Core-Shell Modeling of Light Scattering by Vesicles: Effect of Size, Contents, and Lamellarity. Biophysical Journal 116, 659–669. PDF

2018 

Kim, S.C., O’Flaherty, D.K., Zhou, L., Lelyveld, V.S., Szostak, J.W.*, 2018. Inosine, but none of the 8-oxo-purines, is a plausible component of a primordial version of RNA. Proc. Natl. Acad. Sci. U.S.A. 115, 13318–13323. PDF 

Jin, L., Engelhart, A.E., Zhang, W., Adamala, K., Szostak, J.W.*, 2018. Catalysis of Template-Directed Nonenzymatic RNA Copying by Iron(II). J. Am. Chem. Soc. 140, 15016–15021. PDF

Joyce, G.F.*, Szostak, J.W.*, 2018. Protocells and RNA Self-Replication. Cold Spring Harb Perspect Biol 10, a034801. PDF

Giurgiu, C., Wright, T.H., O’Flaherty, D.K., Szostak, J.W.,* 2018. A Fluorescent G‐Quadruplex Sensor for Chemical RNA Copying. Angew Chem Int Ed 57, 9844–9848. PDF

Zhang, W., Walton, T., Li, L., Szostak, J.W.*, 2018. Crystallographic observation of nonenzymatic RNA primer extension. eLife 7, e36422. PDF

O’Flaherty, D.K., Kamat, N.P.*, Mirza, F.N., Li, L., Prywes, N., Szostak, J.W.*, 2018. Copying of Mixed-Sequence RNA Templates inside Model Protocells. J. Am. Chem. Soc. 140, 5171–5178. PDF

Jin, L.#, Engelhart, A.E.#, Adamala, K.P., Szostak, J.W.*, 2018. Preparation, Purification, and Use of Fatty Acid-containing Liposomes. JoVE 57324. PDF 

Jin, L., Kamat, N.P., Jena, S., Szostak, J.W.*, 2018. Fatty Acid/Phospholipid Blended Membranes: A Potential Intermediate State in Protocellular Evolution. Small 14, 1704077. PDF

Zhang, W., Tam, C.P., Zhou, L., Oh, S.S., Wang, J., Szostak, J.W., 2018. Structural Rationale for the Enhanced Catalysis of Nonenzymatic RNA Primer Extension by a Downstream Oligonucleotide. J. Am. Chem. Soc. 140, 2829–2840. PDF

Todd, Z.R.*, Fahrenbach, A.C., Magnani, C.J., Ranjan, S., Björkbom, A., Szostak, J.W., Sasselov, D.D., 2018. Solvated-electron production using cyanocuprates is compatible with the UV-environment on a Hadean–Archaean Earth. Chem. Commun. 54, 1121–1124. PDF

Tam, C.P., Zhou, L., Fahrenbach, A.C., Zhang, W., Walton, T., Szostak, J.W.*, 2018. Synthesis of a Nonhydrolyzable Nucleotide Phosphoroimidazolide Analogue That Catalyzes Nonenzymatic RNA Primer Extension. J. Am. Chem. Soc. 140, 783–792. PDF

2017

Giurgiu, C., Li, L., O’Flaherty, D.K., Tam, C.P., Szostak, J.W.*, 2017. A Mechanistic Explanation for the Regioselectivity of Nonenzymatic RNA Primer Extension. J. Am. Chem. Soc. 139, 16741–16747. PDF 

Walton, T., Szostak, J.W.*, 2017. A Kinetic Model of Nonenzymatic RNA Polymerization by Cytidine-5′-phosphoro-2-aminoimidazolide. Biochemistry 56, 5739–5747. PDF

Ransey, E., Björkbom, A., Lelyveld, V.S., Biecek, P., Pantano, L., Szostak, J.W., Sliz, P.*, 2017. Comparative analysis of LIN28-RNA binding sites identified at single nucleotide resolution. RNA Biology 14, 1756–1765. PDF

Bonfio, C., Valer, L., Scintilla, S., Shah, S., Evans, D.J., Jin, L., Szostak, J.W., Sasselov, D.D., Sutherland, J.D., Mansy, S.S.*, 2017. UV-light-driven prebiotic synthesis of iron–sulfur clusters. Nature Chem 9, 1229–1234. PDF

Zhang, W., Tam, C.P., Walton, T., Fahrenbach, A.C., Birrane, G., Szostak, J.W.*, 2017. Insight into the mechanism of nonenzymatic RNA primer extension from the structure of an RNA-GpppG complex. Proc. Natl. Acad. Sci. U.S.A. 114, 7659–7664. PDF

Fahrenbach, A.C., Giurgiu, C., Tam, C.P., Li, L., Hongo, Y., Aono, M., Szostak, J.W.*, 2017. Common and Potentially Prebiotic Origin for Precursors of Nucleotide Synthesis and Activation. J. Am. Chem. Soc. 139, 8780–8783. PDF

Stairs, S., Nikmal, A., Bučar, D.-K., Zheng, S.-L., Szostak, J.W.*, Powner, M.W.*, 2017. Divergent prebiotic synthesis of pyrimidine and 8-oxo-purine ribonucleotides. Nat Commun 8, 15270. PDF

Szostak, J.W.*, 2017. The Narrow Road to the Deep Past: In Search of the Chemistry of the Origin of Life. Angew Chem Int Ed 56, 11037–11043. PDF

Li, L., Prywes, N., Tam, C.P., O’Flaherty, D.K., Lelyveld, V.S., Izgu, E.C., Pal, A., Szostak, J.W.*, 2017. Enhanced Nonenzymatic RNA Copying with 2-Aminoimidazole Activated Nucleotides. J. Am. Chem. Soc. 139, 1810–1813. PDF 

Tam, C.P., Fahrenbach, A.C., Björkbom, A., Prywes, N., Izgu, E.C., Szostak, J.W.*, 2017. Downstream Oligonucleotides Strongly Enhance the Affinity of GMP to RNA Primer–Template Complexes. J. Am. Chem. Soc. 139, 571–574. PDF

2016 

Zhang, W., Tam, C.P., Wang, J., Szostak, J.W.*, 2016. Unusual Base-Pairing Interactions in Monomer–Template Complexes. ACS Cent. Sci. 2, 916–926. PDF

Izgu, E.C., Björkbom, A., Kamat, N.P., Lelyveld, V.S., Zhang, W., Jia, T.Z., Szostak, J.W.*, 2016. N -Carboxyanhydride-Mediated Fatty Acylation of Amino Acids and Peptides for Functionalization of Protocell Membranes. J. Am. Chem. Soc. 138, 16669–16676. PDF

Pal, A., Das, R.S., Zhang, W., Lang, M., McLaughlin, L.W., Szostak, J.W.*, 2016. Effect of terminal 3′-hydroxymethyl modification of an RNA primer on nonenzymatic primer extension. Chem. Commun. 52, 11905–11907. PDF 

Walton, T., Szostak, J.W.*, 2016. A Highly Reactive Imidazolium-Bridged Dinucleotide Intermediate in Nonenzymatic RNA Primer Extension. J. Am. Chem. Soc. 138, 11996–12002. PDF

Prywes, N., Blain, J.C., Del Frate, F., Szostak, J.W.*, 2016. Nonenzymatic copying of RNA templates containing all four letters is catalyzed by activated oligonucleotides. eLife 5, e17756. PDF

Prywes, N., Michaels, Y.S., Pal, A., Oh, S.S., Szostak, J.W.*, 2016. Thiolated uridine substrates and templates improve the rate and fidelity of ribozyme-catalyzed RNA copying. Chem. Commun. 52, 6529–6532. PDF

Engelhart, A.E., Adamala, K.P., Szostak, J.W.*, 2016. A simple physical mechanism enables homeostasis in primitive cells. Nature Chem 8, 448–453. PDF

Adamala, K.P., Engelhart, A.E., Szostak, J.W.*, 2016. Collaboration between primitive cell membranes and soluble catalysts. Nat Commun 7, 11041. PDF

Li, L., Lelyveld, V.S., Prywes, N., Szostak, J.W.*, 2016. Experimental and Computational Evidence for a Loose Transition State in Phosphoroimidazolide Hydrolysis. J. Am. Chem. Soc. 138, 3986–3989. PDF 

Izgu, E.C., Oh, S.S., Szostak, J.W.*, 2016. Synthesis of activated 3′-amino-3′-deoxy-2-thio-thymidine, a superior substrate for the nonenzymatic copying of nucleic acid templates. Chem. Commun. 52, 3684–3686. PDF

2015 

Lelyveld, V.S., Björkbom, A., Ransey, E.M., Sliz, P., Szostak, J.W.*, 2015. Pinpointing RNA-Protein Cross-Links with Site-Specific Stable Isotope-Labeled Oligonucleotides. J. Am. Chem. Soc. 137, 15378–15381. PDF

Björkbom, A., Lelyveld, V.S., Zhang, S., Zhang, W., Tam, C.P., Blain, J.C., Szostak, J.W.*, 2015. Bidirectional Direct Sequencing of Noncanonical RNA by Two-Dimensional Analysis of Mass Chromatograms. J. Am. Chem. Soc. 137, 14430–14438. PDF

Larsen, A.T., Fahrenbach, A.C., Sheng, J., Pian, J., Szostak, J.W.*, 2015. Thermodynamic insights into 2-thiouridine-enhanced RNA hybridization. Nucleic Acids Res 43, 7675–7687. PDF

Kamat, N.P., Tobé, S., Hill, I.T., Szostak, J.W.*, 2015. Electrostatic Localization of RNA to Protocell Membranes by Cationic Hydrophobic Peptides. Angew Chem Int Ed 54, 11735–11739. PDF

Adamala, K., Engelhart, A.E., Kamat, N.P., Jin, L., Szostak, J.W.*, 2015. Construction of a liposome dialyzer for the preparation of high-value, small-volume liposome formulations. Nat Protoc 10, 927–938. PDF

Izgu, E.C., Fahrenbach, A.C., Zhang, N., Li, L., Zhang, W., Larsen, A.T., Blain, J.C., Szostak, J.W.*, 2015. Uncovering the Thermodynamics of Monomer Binding for RNA Replication. J. Am. Chem. Soc. 137, 6373–6382. PDF

Heuberger, B.D., Pal, A., Del Frate, F., Topkar, V.V., Szostak, J.W.*, 2015. Replacing Uridine with 2-Thiouridine Enhances the Rate and Fidelity of Nonenzymatic RNA Primer Extension. J. Am. Chem. Soc. 137, 2769–2775. PDF

Adamala, K., Engelhart, A.E., Szostak, J.W.*, 2015. Generation of Functional RNAs from Inactive Oligonucleotide Complexes by Non-enzymatic Primer Extension. J. Am. Chem. Soc. 137, 483–489. PDF

2014

Hentrich, C., Szostak, J.W.*, 2014. Controlled Growth of Filamentous Fatty Acid Vesicles under Flow. Langmuir 30, 14916–14925. PDF

Budin, I., Prywes, N., Zhang, N., Szostak, J.W.*, 2014. Chain-Length Heterogeneity Allows for the Assembly of Fatty Acid Vesicles in Dilute Solutions. Biophysical Journal 107, 1582–1590. PDF

Sheng, J., Larsen, A., Heuberger, B.D., Blain, J.C., Szostak, J.W.*, 2014. Crystal Structure Studies of RNA Duplexes Containing s 2 U:A and s 2 U:U Base Pairs. J. Am. Chem. Soc. 136, 13916–13924. PDF

Blain, J.C., Szostak, J.W.*, 2014. Progress Toward Synthetic Cells. Annu. Rev. Biochem. 83, 615–640. PDF

Jia, T.Z., Hentrich, C., Szostak, J.W.*, 2014. Rapid RNA Exchange in Aqueous Two-Phase System and Coacervate Droplets. Orig Life Evol Biosph 44, 1–12. PDF

Sheng, J., Li, L., Engelhart, A.E., Gan, J., Wang, J., Szostak, J.W., 2014. Structural insights into the effects of 2′-5′ linkages on the RNA duplex. Proc. Natl. Acad. Sci. U.S.A. 111, 3050–3055. PDF

Li, L., Szostak, J.W., 2014. The Free Energy Landscape of Pseudorotation in 3′–5′ and 2′–5′ Linked Nucleic Acids. J. Am. Chem. Soc. 136, 2858–2865. PDF

Blain, J.C., Ricardo, A., Szostak, J.W., 2014. Synthesis and Nonenzymatic Template-Directed Polymerization of 2′-Amino-2′-deoxythreose Nucleotides. J. Am. Chem. Soc. 136, 2033–2039. PDF

2013

Adamala, K., Szostak, J.W., 2013. Nonenzymatic Template-Directed RNA Synthesis Inside Model Protocells. Science 342, 1098–1100. PDF

Zhu, T.F., Budin, I., Szostak, J.W., 2013. Preparation of Fatty Acid Micelles, in: Methods in Enzymology. Elsevier, pp. 283–288. PDF

Zhu, T.F., Budin, I., Szostak, J.W., 2013. Vesicle Extrusion Through Polycarbonate Track-etched Membranes using a Hand-held Mini-extruder, in: Methods in Enzymology. Elsevier, pp. 275–282. PDF

Zhu, T.F., Budin, I., Szostak, J.W., 2013. Preparation of Fatty Acid or Phospholipid Vesicles by Thin-film Rehydration, in: Methods in Enzymology. Elsevier, pp. 267–274. PDF

Josephson, K., Ricardo, A., Szostak, J.W., 2014. mRNA display: from basic principles to macrocycle drug discovery. Drug Discovery Today 19, 388–399. PDF

Zhang, S., Blain, J.C., Zielinska, D., Gryaznov, S.M., Szostak, J.W., 2013. Fast and accurate nonenzymatic copying of an RNA-like synthetic genetic polymer. Proc. Natl. Acad. Sci. U.S.A. 110, 17732–17737. PDF

Adamala, K., Szostak, J.W., 2013. Competition between model protocells driven by an encapsulated catalyst. Nature Chem 5, 495–501. PDF

Engelhart, A.E., Powner, M.W., Szostak, J.W., 2013. Functional RNAs exhibit tolerance for non-heritable 2′–5′ versus 3′–5′ backbone heterogeneity. Nature Chem 5, 390–394. PDF

Zhang, S., Zhang, N., Blain, J.C., Szostak, J.W., 2013. Synthesis of N3′-P5′-linked Phosphoramidate DNA by Nonenzymatic Template-Directed Primer Extension. J. Am. Chem. Soc. 135, 924–932. PDF

2012

Budin, I., Debnath, A., Szostak, J.W., 2012. Concentration-Driven Growth of Model Protocell Membranes. J. Am. Chem. Soc. 134, 20812–20819. PDF

Powner, M.W.*, Zheng, S.-L., Szostak, J.W., 2012. Multicomponent Assembly of Proposed DNA Precursors in Water. J. Am. Chem. Soc. 134, 13889–13895. PDF

Szostak, J.W., 2012. The eightfold path to non-enzymatic RNA replication. J Syst Chem 3, 2. PDF

Zhu, T.F., Adamala, K., Zhang, N., Szostak, J.W., 2012. Photochemically driven redox chemistry induces protocell membrane pearling and division. Proc. Natl. Acad. Sci. U.S.A. 109, 9828–9832. PDF

Hofmann, F.T., Szostak, J.W., Seebeck, F.P., 2012. In Vitro Selection of Functional Lantipeptides. J. Am. Chem. Soc. 134, 8038–8041. PDF

Guillen Schlippe, Y.V., Hartman, M.C.T., Josephson, K., Szostak, J.W., 2012. In Vitro Selection of Highly Modified Cyclic Peptides That Act as Tight Binding Inhibitors. J. Am. Chem. Soc. 134, 10469–10477. PDF

Zhang, N., Zhang, S., Szostak, J.W., 2012. Activated Ribonucleotides Undergo a Sugar Pucker Switch upon Binding to a Single-Stranded RNA Template. J. Am. Chem. Soc. 134, 3691–3694. PDF

Szostak, J.W., 2012. Attempts to Define Life Do Not Help to Understand the Origin of Life. Journal of Biomolecular Structure and Dynamics 29, 599–600. PDF

2011

Szostak, J.W., 2011. An optimal degree of physical and chemical heterogeneity for the origin of life? Phil. Trans. R. Soc. B 366, 2894–2901. PDF

Seebeck, F.P., Ricardo, A., Szostak, J.W., 2011. Artificial lantipeptides from in vitro translations. Chem. Commun. 47, 6141. PDF

Zhu, T.F., Szostak, J.W., 2011. Exploding vesicles. J Syst Chem 2, 4. PDF

Trevino, S.G., Zhang, N., Elenko, M.P., Lupták, A., Szostak, J.W., 2011. Evolution of functional nucleic acids in the presence of nonheritable backbone heterogeneity. Proc. Natl. Acad. Sci. U.S.A. 108, 13492–13497. PDF

Budin, I., Szostak, J.W., 2011. Physical effects underlying the transition from primitive to modern cell membranes. Proc. Natl. Acad. Sci. U.S.A. 108, 5249–5254. PDF

Subtelny, A.O., Hartman, M.C.T., Szostak, J.W., 2011. Optimal Codon Choice Can Improve the Efficiency and Fidelity of N ‐Methyl Amino Acid Incorporation into Peptides by In‐Vitro Translation. Angew Chem Int Ed 50, 3164–3167. PDF

2010

Powner, M.W., Sutherland, J.D., Szostak, J.W., 2011. Chemoselective Multicomponent One-Pot Assembly of Purine Precursors in Water. J. Am. Chem. Soc. 133, 4149–4150. PDF

Elenko, M.P., Szostak, J.W., Van Oijen, A.M., 2010. Single-molecule binding experiments on long time scales. Review of Scientific Instruments 81, 083705. PDF

Schrum, J.P., Zhu, T.F., Szostak, J.W., 2010. The origins of cellular life. Cold Spring Harb Perspect Biol 2, a002212. PDF

Rajamani, S., Ichida, J.K., Antal, T., Treco, D.A., Leu, K., Nowak, M.A., Szostak, J.W., Chen, I.A., 2010. Effect of Stalling after Mismatches on the Error Catastrophe in Nonenzymatic Nucleic Acid Replication. J. Am. Chem. Soc. 132, 5880–5885. PDF

Budin, I., Szostak, J.W., 2010. Expanding Roles for Diverse Physical Phenomena During the Origin of Life. Annu. Rev. Biophys. 39, 245–263. PDF

2009

Bruckner, R.J., Mansy, S.S., Ricardo, A., Mahadevan, L., Szostak, J.W., 2009. Flip-Flop-Induced Relaxation of Bending Energy: Implications for Membrane Remodeling. Biophysical Journal 97, 3113–3122. PDF

Schrum, J.P., Ricardo, A., Krishnamurthy, M., Blain, J.C., Szostak, J.W., 2009. Efficient and Rapid Template-Directed Nucleic Acid Copying Using 2′-Amino-2′,3′-dideoxyribonucleoside−5′-Phosphorimidazolide Monomers. J. Am. Chem. Soc. 131, 14560–14570. PDF

Mansy, S.S., Szostak, J.W., 2009. Reconstructing the Emergence of Cellular Life through the Synthesis of Model Protocells. Cold Spring Harbor Symposia on Quantitative Biology 74, 47–54. PDF

Lin, S., Horning, D.P., Szostak, J.W., Chaput, J.C., 2009. Conformational Analysis of DNA Repair Intermediates by Time-Resolved Fluorescence Spectroscopy. J. Phys. Chem. A 113, 9585–9587. PDF

Budin, I., Bruckner, R.J., Szostak, J.W., 2009. Formation of Protocell-like Vesicles in a Thermal Diffusion Column. J. Am. Chem. Soc. 131, 9628–9629. PDF

Elenko, M.P., Szostak, J.W., Van Oijen, A.M., 2009. Single-Molecule Imaging of an in Vitro -Evolved RNA Aptamer Reveals Homogeneous Ligand Binding Kinetics. J. Am. Chem. Soc. 131, 9866–9867. PDF

Szostak, J.W., 2009. Systems chemistry on early Earth. Nature 459, 171–172. PDF

Zhu, T.F., Szostak, J.W., 2009. Preparation of Large Monodisperse Vesicles. PLoS ONE 4, e5009. PDF

Zhu, T.F., Szostak, J.W., 2009. Coupled Growth and Division of Model Protocell Membranes. J. Am. Chem. Soc. 131, 5705–5713. PDF

Chen, J.J., Tsai, C.-H., Cai, X., Horhota, A.T., McLaughlin, L.W., Szostak, J.W., 2009. Enzymatic Primer-Extension with Glycerol-Nucleoside Triphosphates on DNA Templates. PLoS ONE 4, e4949. PDF

Chen, J.J., Cai, X., Szostak, J.W., 2009. N2′→P3′ Phosphoramidate Glycerol Nucleic Acid as a Potential Alternative Genetic System. J. Am. Chem. Soc. 131, 2119–2121. PDF

2008

Mansy, S.S., Szostak, J.W., 2008. Thermostability of model protocell membranes. Proc. Natl. Acad. Sci. U.S.A. 105, 13351–13355. PDF

Mansy, S.S., Schrum, J.P., Krishnamurthy, M., Tobé, S., Treco, D.A., Szostak, J.W., 2008. Template-directed synthesis of a genetic polymer in a model protocell. Nature 454, 122–125. PDF

Subtelny, A.O., Hartman, M.C.T., Szostak, J.W., 2008. Ribosomal Synthesis of N -Methyl Peptides. J. Am. Chem. Soc. 130, 6131–6136. PDF

Monnard, P.-A., Szostak, J.W., 2008. Metal-ion catalyzed polymerization in the eutectic phase in water–ice: A possible approach to template-directed RNA polymerization. Journal of Inorganic Biochemistry 102, 1104–1111. PDF

2007

Hartman, M.C.T., Josephson, K., Lin, C.-W., Szostak, J.W., 2007. An Expanded Set of Amino Acid Analogs for the Ribosomal Translation of Unnatural Peptides. PLoS ONE 2, e972. PDF

Tsai, C.-H., Chen, J., Szostak, J.W., 2007. Enzymatic synthesis of DNA on glycerol nucleic acid templates without stable duplex formation between product and template. Proc. Natl. Acad. Sci. U.S.A. 104, 14598–14603. PDF

Seelig, B., Szostak, J.W., 2007. Selection and evolution of enzymes from a partially randomized non-catalytic scaffold. Nature 448, 828–831. PDF

Mansy, S.S., Zhang, J., Kümmerle, R., Nilsson, M., Chou, J.J., Szostak, J.W., Chaput, J.C., 2007. Structure and Evolutionary Analysis of a Non-biological ATP-binding Protein. Journal of Molecular Biology 371, 501–513. PDF

Smith, M.D., Rosenow, M.A., Wang, M., Allen, J.P., Szostak, J.W., Chaput, J.C., 2007. Structural Insights into the Evolution of a Non-Biological Protein: Importance of Surface Residues in Protein Fold Optimization. PLoS ONE 2, e467. PDF

Hazen, R.M., Griffin, P.L., Carothers, J.M., Szostak, J.W., 2007. Functional information and the emergence of biocomplexity. Proc. Natl. Acad. Sci. U.S.A. 104, 8574–8581. PDF

Meena, Sam, M., Pierce, K., Szostak, J.W., McLaughlin, L.W., 2007. 2‘,3‘-Dideoxy-3‘-thionucleoside Triphosphates: Syntheses and Polymerase Substrate Activities. Org. Lett. 9, 1161–1163. PDF

2006

Horhota, A.T., Szostak, J.W., McLaughlin, L.W., 2006. Glycerol Nucleoside Triphosphates: Synthesis and Polymerase Substrate Activities. Org. Lett. 8, 5345–5347. PDF

Blackburn, E.H., Greider, C.W., Szostak, J.W., 2006. Telomeres and telomerase: the path from maize, Tetrahymena and yeast to human cancer and aging. Nat Med 12, 1133–1138. PDF

Salehi-Ashtiani, K., Lupták, A., Litovchick, A., Szostak, J.W., 2006. A Genomewide Search for Ribozymes Reveals an HDV-Like Sequence in the Human CPEB3 Gene. Science 313, 1788–1792. PDF

Hanczyc, M.M., Mansy, S.S., Szostak, J.W., 2007. Mineral Surface Directed Membrane Assembly. Orig Life Evol Biosph 37, 67–82. PDF

Carothers, J.M., Oestreich, S.C., Szostak, J.W., 2006. Aptamers Selected for Higher-Affinity Binding Are Not More Specific for the Target Ligand. J. Am. Chem. Soc. 128, 7929–7937. PDF

Seebeck, F.P., Szostak, J.W., 2006. Ribosomal Synthesis of Dehydroalanine-Containing Peptides. J. Am. Chem. Soc. 128, 7150–7151. PDF

Hartman, M.C.T., Josephson, K., Szostak, J.W., 2006. Enzymatic aminoacylation of tRNA with unnatural amino acids. Proc. Natl. Acad. Sci. U.S.A. 103, 4356–4361. PDF

Carothers, J.M., Davis, J.H., Chou, J.J., Szostak, J.W., 2006. Solution structure of an informationally complex high-affinity RNA aptamer to GTP. RNA 12, 567–579. PDF

Cho, G.S., Szostak, J.W., 2006. Directed Evolution of ATP Binding Proteins from a Zinc Finger Domain by Using mRNA Display. Chemistry & Biology 13, 139–147. PDF

2005

Fujikawa, S.M., Chen, I.A., Szostak, J.W., 2005. Shrink-Wrap Vesicles. Langmuir 21, 12124–12129. PDF

Plummer, K.A., 2005. In vitro selection of RNA aptamers against a composite small molecule-protein surface. Nucleic Acids Research 33, 5602–5610. PDF

Chen, I.A., Salehi-Ashtiani, K., Szostak, J.W., 2005. RNA Catalysis in Model Protocell Vesicles. J. Am. Chem. Soc. 127, 13213–13219. PDF

Ichida, J.K., 2005. High fidelity TNA synthesis by Therminator polymerase. Nucleic Acids Research 33, 5219–5225. PDF

Josephson, K., Hartman, M.C.T., Szostak, J.W., 2005. Ribosomal Synthesis of Unnatural Peptides. J. Am. Chem. Soc. 127, 11727–11735. PDF

Horhota, A., Zou, K., Ichida, J.K., Yu, B., McLaughlin, L.W., Szostak, J.W., Chaput, J.C., 2005. Kinetic Analysis of an Efficient DNA-Dependent TNA Polymerase. J. Am. Chem. Soc. 127, 7427–7434. PDF

Shen, X., Valencia, C.A., Szostak, J., Dong, B., Liu, R., 2005. Scanning the human proteome for calmodulin-binding proteins. Proc. Natl. Acad. Sci. U.S.A. 102, 5969–5974. PDF correction

Sacerdote, M.G., Szostak, J.W., 2005. Semipermeable lipid bilayers exhibit diastereoselectivity favoring ribose. Proc. Natl. Acad. Sci. U.S.A. 102, 6004–6008. PDF

Zou, K., Horhota, A., Yu, B., Szostak, J.W., McLaughlin, L.W., 2005. Synthesis of α- l -Threofuranosyl Nucleoside Triphosphates (tNTPs). Org. Lett. 7, 1485–1487. PDF

Ichida, J.K., Zou, K., Horhota, A., Yu, B., McLaughlin, L.W., Szostak, J.W., 2005. An in Vitro Selection System for TNA. J. Am. Chem. Soc. 127, 2802–2803. PDF

2004

Hanczyc, M.M., Szostak, J.W., 2004. Replicating vesicles as models of primitive cell growth and division. Current Opinion in Chemical Biology 8, 660–664. PDF

Chen, I.A., Roberts, R.W., Szostak, J.W., 2004. The Emergence of Competition Between Model Protocells. Science 305, 1474–1476. PDF

Chen, I.A., Szostak, J.W., 2004. A Kinetic Study of the Growth of Fatty Acid Vesicles. Biophysical Journal 87, 988–998. PDF

Sazani, P.L., Larralde, R., Szostak, J.W., 2004. A Small Aptamer with Strong and Specific Recognition of the Triphosphate of ATP. J. Am. Chem. Soc. 126, 8370–8371. PDF

Chaput, J.C., Szostak, J.W., 2004. Evolutionary Optimization of a Nonbiological ATP Binding Protein for Improved Folding Stability. Chemistry & Biology 11, 865–874. PDF

Chen, I.A., Szostak, J.W., 2004. Membrane growth can generate a transmembrane pH gradient in fatty acid vesicles. Proc. Natl. Acad. Sci. U.S.A. 101, 7965–7970. PDF

Carothers, J.M., Oestreich, S.C., Davis, J.H., Szostak, J.W., 2004. Informational Complexity and Functional Activity of RNA Structures. J. Am. Chem. Soc. 126, 5130–5137. PDF

2003

Hanczyc, M.M., Fujikawa, S.M., Szostak, J.W., 2003. Experimental Models of Primitive Cellular Compartments: Encapsulation, Growth, and Division. Science 302, 618–622. PDF

Chaput, J.C., Szostak, J.W., 2003. TNA Synthesis by DNA Polymerases. J. Am. Chem. Soc. 125, 9274–9275. PDF

Vaish, N.K., Larralde, R., Fraley, A.W., Szostak, J.W., McLaughlin, L.W., 2003. A Novel, Modification-Dependent ATP-Binding Aptamer Selected from an RNA Library Incorporating a Cationic Functionality. Biochemistry 42, 8842–8851. PDF

Szostak, J.W., 2003. Functional information: Molecular messages. Nature 423, 689–689. PDF

Huang, Z., Szostak, J.W., 2003. Selective labeling and detection of specific RNAs in an RNA mixture. Analytical Biochemistry 315, 129–133. PDF

Chaput, J.C., Ichida, J.K., Szostak, J.W., 2003. DNA Polymerase-Mediated DNA Synthesis on a TNA Template. J. Am. Chem. Soc. 125, 856–857. PDF

2002

Davis, J.H., Szostak, J.W., 2002. Isolation of high-affinity GTP aptamers from partially structured RNA libraries. Proc. Natl. Acad. Sci. U.S.A. 99, 11616–11621. PDF

Baggio, R., Burgstaller, P., Hale, S.P., Putney, A.R., Lane, M., Lipovsek, D., Wright, M.C., Roberts, R.W., Liu, R., Szostak, J.W., Wagner, R.W., 2002. Identification of epitope‐like consensus motifs using mRNA display. J of Molecular Recognition 15, 126–134. PDF

2001

Salehi-Ashtiani, K., Szostak, J.W., 2001. In vitro evolution suggests multiple origins for the hammerhead ribozyme. Nature 414, 82–84. PDF

Szostak, J.W., Bartel, D.P., Luisi, P.L., 2001. Synthesizing life. Nature 409, 387–390. PDF

Keefe, A.D., Szostak, J.W., 2001. Functional proteins from a random-sequence library. Nature 410, 715–718. PDF

Keefe, A.D., Wilson, D.S., Seelig, B., Szostak, J.W., 2001. One-Step Purification of Recombinant Proteins Using a Nanomolar-Affinity Streptavidin-Binding Peptide, the SBP-Tag. Protein Expression and Purification 23, 440–446. PDF

Wilson, D.S., Keefe, A.D., Szostak, J.W., 2001. The use of mRNA display to select high-affinity protein-binding peptides. Proc. Natl. Acad. Sci. U.S.A. 98, 3750–3755. PDF

2000

Cho, G., Keefe, A.D., Liu, R., Wilson, D.S., Szostak, J.W., 2000. Constructing high complexity synthetic libraries of long ORFs using In Vitro selection. Journal of Molecular Biology 297, 309–319. PDF

Vaish, N.K., 2000. Expanding the structural and functional diversity of RNA: analog uridine triphosphates as candidates for in vitro selection of nucleic acids. Nucleic Acids Research 28, 3316–3322. PDF

Suga, H., Lee, N., Bessho, Y., Wei, K., Szostak, J.W., 2000. Ribozyme-catalyzed tRNA aminoacylation. Nat. Struct Biol. 7, 28–33. PDF

Liu, R., Barrick, J.E., Szostak, J.W., Roberts, R.W., 2000. [19] Optimized synthesis of RNA-protein fusions for in vitro protein selection, in: Methods in Enzymology. Elsevier, pp. 268–293. PDF

1999

Wilson, D.S., Szostak, J.W., 1999. In Vitro Selection of Functional Nucleic Acids. Annu. Rev. Biochem. 68, 611–647. PDF

1998

Samuelson, J.C. (Ed.), 2013. Enzyme engineering: methods and protocols, Methods in molecular biology. Humana Press, New York, N.Y. Heidelberg. PDF

Holeman, L.A., Robinson, S.L., Szostak, J.W., Wilson, C., 1998. Isolation and characterization of fluorophore-binding RNA aptamers. Folding and Design 3, 423–431. PDF

Wilson, C., Szostak, J.W., 1998. Isolation of a fluorophore-specific DNA aptamer with weak redox activity. Chemistry & Biology 5, 609–617. PDF

Wilson, C., Nix, J., Szostak, J., 1998. Functional Requirements for Specific Ligand Recognition by a Biotin-Binding RNA Pseudoknot. Biochemistry 37, 14410–14419. PDF

Suga, H., Cowan, J.A., Szostak, J.W., 1998. Unusual Metal Ion Catalysis in an Acyl-Transferase Ribozyme. Biochemistry 37, 10118–10125. PDF

Suga, H., Lohse, P.A., Szostak, J.W., 1998. Structural and Kinetic Characterization of an Acyl Transferase Ribozyme. J. Am. Chem. Soc. 120, 1151–1156. PDF

1997

Roberts, R.W., Szostak, J.W., 1997. RNA-peptide fusions for the in vitro selection of peptides and proteins. Proc. Natl. Acad. Sci. U.S.A. 94, 12297–12302. PDF

Hager, A.J., Szostak, J.W., 1997. Isolation of novel ribozymes that ligate AMP-activated RNA substrates. Chemistry & Biology 4, 607–617. PDF

Dieckmann, T., Butcher, S.E., Sassanfar, M., Szostak, J.W., Feigon, J., 1997. Mutant ATP-binding RNA aptamers reveal the structural basis for ligand binding. Journal of Molecular Biology 273, 467–478. PDF

Szostak, J.W., 1997. Introduction: Combinatorial Chemistry. Chem. Rev. 97, 347–348. PDF

1996

Hager, A.J., Pollard, J.D., Szostak, J.W., 1996. Ribozymes: aiming at RNA replication and protein synthesis. Chemistry & Biology 3, 717–725. PDF

Huang, Z., 1996. A simple method for 3’-labeling of RNA. Nucleic Acids Research 24, 4360–4361. PDF

Lohse, P.A., Szostak, J.W., 1996. Ribozyme-catalysed amino-acid transfer reactions. Nature 381, 442–444. PDF

Rohatgi, R., Bartel, D.P., Szostak, J.W., 1996. Nonenzymatic, Template-Directed Ligation of Oligoribonucleotides Is Highly Regioselective for the Formation of 3‘−5‘ Phosphodiester Bonds. J. Am. Chem. Soc. 118, 3340–3344. PDF

Rohatgi, R., Bartel, D.P., Szostak, J.W., 1996. Kinetic and Mechanistic Analysis of Nonenzymatic, Template-Directed Oligoribonucleotide Ligation. J. Am. Chem. Soc. 118, 3332–3339. PDF

Lorsch, J.R., Szostak, J.W., 1996. Chance and Necessity in the Selection of Nucleic Acid Catalysts. Acc. Chem. Res. 29, 103–110. PDF

Wilson, D.S., Szostak, J.W., 1999. In Vitro Selection of Functional Nucleic Acids. Annu. Rev. Biochem. 68, 611–647. PDF

1995

Lorsch, J.R., Bartel, D.P., Szostak, J.W., 1995. Reverse transcriptase reads through a 2′–5′ linkage and a 2′-thiphosphate in a template. Nucl Acids Res 23, 2811–2814. PDF

Ekland, E.H., Szostak, J.W., Bartel, D.P., 1995. Structurally Complex and Highly Active RNA Ligases Derived from Random RNA Sequences. Science 269, 364–370. PDF

Cuenoud, B., Szostak, J.W., 1995. A DNA metalloenzyme with DNA ligase activity. Nature 375, 611–614. PDF

Chapman, K.B., Szostak, J.W., 1995. Isolation of a ribozyme with 5′-5′ ligase activity. Chemistry & Biology 2, 325–333. PDF

Wilson, C., Szostak, J.W., 1995. In vitro evolution of a self-alkylatlng ribozyme. Nature 374, 777–782. PDF

Whoriskey, S.K., Usman, N., Szostak, J.W., 1995. Total chemical synthesis of a ribozyme derived from a group I intron. Proc. Natl. Acad. Sci. U.S.A. 92, 2465–2469. PDF

Lauhon, C.T., Szostak, J.W., 1995. RNA aptamers that bind flavin and nicotinamide redox cofactors. J. Am. Chem. Soc. 117, 1246–1257. PDF

Huizenga, D.E., Szostak, J.W., 1995. A DNA Aptamer That Binds Adenosine and ATP. Biochemistry 34, 656–665. PDF

1994

Hanna, M., Szostak, J.W., 1994. Suppression of mutations in the core of the Tetrahymena ribozyme by spermidine, ethanol and by substrate stabilization. Nucl Acids Res 22, 5326–5331. PDF

Lorsch, J.R., Szostak, J.W., 1994. In vitro evolution of new ribozymes with polynucleotide kinase activity. Nature 371, 31–36. PDF

Chapman, K.B., Szostak, J.W., 1994. In vitro selection of catalytic RNAs. Current Opinion in Structural Biology 4, 618–622. PDF

Peterson, R.D., Bartel, D.P., Szostak, J.W., Horvath, S.J., Feigon, J., 1994. 1H NMR studies of the high-affinity Rev binding site of the Rev responsive element of HIV-1 mRNA: base pairing in the core binding element. Biochemistry 33, 5357–5366. PDF

Lorsch, J.R., Szostak, J.W., 1994. In vitro selection of RNA aptamers specific for cyanocobalamin. Biochemistry 33, 973–982. PDF

Lin, C.W., Hanna, M., Szostak, J.W., 1994. Evidence That the Guanosine Substrate of the Tetrahymena Ribozyme Is Bound in the Anti Conformation and That N7 Contributes to Binding. Biochemistry 33, 2703–2707. PDF

Green, R., Szostak, J.W., 1994. In vitro genetic analysis of the hinge region between helical elements P5-P4-P6 and P7-P3-P8 in the sunY group I self-splicing intron. Journal of Molecular Biology 235, 140–155. PDF

1993

Bartel, D.P., Szostak, J.W., 1993. Isolation of New Ribozymes from a Large Pool of Random Sequences. Science 261, 1411–1418. PDF

Sassanfar, M., Szostak, J.W., 1993. An RNA motif that binds ATP. Nature 364, 550–553. PDF

Doudna, J.A., Usman, N., Szostak, J.W., 1993. Ribozyme-catalyzed primer extension by trinucleotides: A model for the RNA-catalyzed replication of RNA. Biochemistry 32, 2111–2115. PDF

1992

Green, R., Szostak, J.W., 1992. Selection of a Ribozyme That Functions as a Superior Template in a Self-Copying Reaction. Science 258, 1910–1915. PDF

Famulok, M., Szostak, J.W., 1992. In Vitro Selection of Specific Ligand‐binding Nucleic Acids. Angew. Chem. Int. Ed. Engl. 31, 979–988. PDF

Famulok, M., Szostak, J.W., 1992. Stereospecific recognition of tryptophan agarose by in vitro selected RNA. J. Am. Chem. Soc. 114, 3990–3991. PDF

Szostak, J.W., 1992. In vitro genetics. Trends in Biochemical Sciences 17, 89–93. PDF

Ellington, A.D., Szostak, J.W., 1992. Selection in vitro of single-stranded DNA molecules that fold into specific ligand-binding structures. Nature 355, 850–852. PDF

1991

Green, R., Szostak, J.W., Benner, S.A., Rich, A., Usman, N., 1991. Synthesis of RNA containing inosine: analysis of the sequence requirements for the 5′ splice site of the Tetrahymena group I intron. Nucl Acids Res 19, 4161–4166. PDF

Bartel, D.P., Zapp, M.L., Green, M.R., Szostak, J.W., 1991. HIV-1 rev regulation involves recognition of non-Watson-Crick base pairs in viral RNA. Cell 67, 529–536. PDF

Green, R., Ellington, A., Bartel, D., Szostak, J., 1991. In vitro genetic analysis: Selection and amplification of rare functional nucleic acids. Methods 2, 75–86. PDF

Bartel, D.P., Doudna, J.A., Usman, N., Szostak, J.W., 1991. Template-directed primer extension catalyzed by the Tetrahymena ribozyme. Mol. Cell. Biol. 11, 3390–3394. PDF

Doudna, J.A., Couture, S., Szostak, J.W., 1991. A Multisubunit Ribozyme That Is a Catalyst of and Template for Complementary Strand RNA synthesis. Science 251, 1605–1608. PDF

1990

Doudna, J.A., Szostak, J.W., Rich, A., Usman, N., 1990. Chemical synthesis of oligoribonucleotides containing 2-aminopurine: substrates for the investigation of ribozyme function. J. Org. Chem. 55, 5547–5549. PDF

Michel, F., Ellington, A.D., Couture, S., Szostak, J.W., 1990. Phylogenetic and genetic evidence for base-triples in the catalytic domain of group I introns. Nature 347, 578–580. PDF

Ellington, A.D., Szostak, J.W., 1990. In vitro selection of RNA molecules that bind specific ligands. Nature 346, 818–822. PDF

1989

Doudna, J.A., Szostak, J.W., 1989. Miniribozymes, small derivatives of the sunY intron, are catalytically active. Mol. Cell. Biol. 9, 5480–5483. PDF

Rajagopal, J., Doudna, J.A., Szostak, J.W., 1989. Stereochemical Course of Catalysis by the Tetrahymena Ribozyme. Science 244, 692–694. PDF

1987

Doudna, J.A., Gerber, A.S., Cherry, J.M., Szostak, J.W., 1987. Genetic Dissection of an RNA Enzyme. Cold Spring Harbor Symposia on Quantitative Biology 52, 173–180. PDF

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